Train Spain schedules

Locate your departure train on

We are travelling yo Spain in August. Flying into Madrid then taking a train from Madrid - Valencia then Valencia - Barcelona. I am trying to book train tickets online in advance and I can find a lot of schedules now for the first trip but always comes back with an error message or " no routes available" for the Valencia - Barcelona trip. I assumed there would be trains for this route? Do I need to find another way to travel to Barcelona? Also, any suggestions on which "class" of seats I should reserve? Economy (second class) or Comfort (first class) I am travelling with my husband, two children and mother.

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